The Surface Waters (Abstraction for Drinking Water) (Classification) (Scotland) Regulations 1996

Type Statutory-Instrument
Publication 1996-12-03
State In force
Department Queen's Printer of Acts of Parliament
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articles Not indexed
Reform history JSON API

Made: 3rd December 1996

Laid before Parliament: 16th December 1996

Coming into force: 6th January 1997

The Secretary of State, in exercise of the powers conferred on him by sections 30B and 41 of the Control of Pollution Act 1974[^f00001], and, being a Minister designated[^f00002] for the purposes of section 2(2) of the European Communities Act 1972[^f00003] in relation to measures relating to the prevention, reduction and elimination of pollution of water, in exercise of the powers conferred on him by that section, hereby makes the following Regulations:

Citation, commencement, interpretation and extent

1

Classification of waters

2

The classifications DW1, DW2 and DW3 and the criteria for those classifications set out in Schedule 1 shall apply for classifying inland waters by reference to their suitability for abstraction for supply as drinking water.

Guideline values

3

In discharging their functions SEPA and the water authorities shall endeavour to respect the guideline values specified in Schedule 2 for waters of the relevant class.

No deterioration principle

4

Implementation of measures taken pursuant to the 1975 Directive may under no circumstances lead directly or indirectly to deterioration of the current quality of surface water.

Compliance with relevant limits

5

Compliance with guideline values

6

Waivers

7

8

Sampling and analysis

9

Reduction of frequency of sampling etc

10

11

Systematic plan of action

12

SEPA shall draw up and maintain a systematic plan of action including a timetable for the improvement of surface water for the purposes of article 4 of the 1975 Directive.

Information

13

SEPA may serve on any person a notice requiring that person to furnish SEPA, within a period or at times specified in the notice, and in a form and manner so specified, with such information as is reasonably required by SEPA for the purposes of giving effect to the 1975 Directive and the 1979 Directive.

Registers

14

Modification of the Control of Pollution Act 1974

15

Consequential amendments and revocations

16

SCHEDULE 1 — CRITERIA FOR CLASSIFICATION OF WATERS

The limits set out below are maxima

No in Annex II to the 1975 Directive Parameters Parameters DW1 DW2 DW3
(0) See regulation 7(1)(b) (0) See regulation 7(1)(b) (0) See regulation 7(1)(b) (0) See regulation 7(1)(b) (0) See regulation 7(1)(b) (0) See regulation 7(1)(b)
* See regulation 7(1)(d) * See regulation 7(1)(d) * See regulation 7(1)(d) * See regulation 7(1)(d) * See regulation 7(1)(d) * See regulation 7(1)(d)
2 Colouration (after simple filtration) mg/1 Pt Scale 20[^f01000] 100[^f01000] 200[^f01000]
4 Temperature °C 25[^f01000] 25[^f01000] 25[^f01000]
7[^f01001] Nitrates mg/1 NO₃ 50[^f01000] 50[^f01000] 50[^f01000]
8 Fluorides mg/1 F 1.5
10[^f01001] Dissolved iron mg/1 Fe 0.3 2
12 Copper mg/1 Cu 0.05[^f01000]
13 Zinc mg/1 Zn 3 5 5
19 Arsenic mg/1 As 0.05 0.05 0.1
20 Cadmium mg/1 Cd 0.005 0.005 0.005
21 Total Chromium mg/1 Cr 0.05 0.05 0.05
22 Lead mg/1 Pb 0.05 0.05 0.05
23 Selenium mg/1 Se 0.01 0.01 0.01
24 Mercury mg/1 Hg 0.001 0.001 0.001
25 Barium mg/1 Ba 0.1 1 1
26 Cyanide mg/1 CN 0.05 0.05 0.05
27 Sulphates mg/1 SO₄ 250 250[^f01000] 250[^f01000]
31 Phenols (phenol index) paranitroaniline 4-aminoantipyrine mg/1 C₆H₅OH 0.001 0.005 0.1
32 Dissolved or emulsified hydro carbons (after extraction by petroleum ether) mg/1 0.05 0.2 1
33 Polycyclic aro matic hydrocar bons mg/1 0.0002 0.0002 0.001
34 Total pesticides (parathion, hexachlorocyclohexane, dieldrin) mg/1 0.001 0.0025 0.005
39 Ammonia mg/1 NH₄ 1.5 4[^f01000]

SCHEDULE 2 — GUIDELINE VALUES

No in Annex II to 75/440/EEC Parameters Parameters DW1 DW2 DW3
1 The value given is an upper limit set in relation to the mean annual temperature (high and low). 1 The value given is an upper limit set in relation to the mean annual temperature (high and low). 1 The value given is an upper limit set in relation to the mean annual temperature (high and low). 1 The value given is an upper limit set in relation to the mean annual temperature (high and low). 1 The value given is an upper limit set in relation to the mean annual temperature (high and low). 1 The value given is an upper limit set in relation to the mean annual temperature (high and low).
2 This parameter has been included to satisfy the ecological requirements of certain types of environment. 2 This parameter has been included to satisfy the ecological requirements of certain types of environment. 2 This parameter has been included to satisfy the ecological requirements of certain types of environment. 2 This parameter has been included to satisfy the ecological requirements of certain types of environment. 2 This parameter has been included to satisfy the ecological requirements of certain types of environment. 2 This parameter has been included to satisfy the ecological requirements of certain types of environment.
* See regulation 8(1)(c) * See regulation 8(1)(c) * See regulation 8(1)(c) * See regulation 8(1)(c) * See regulation 8(1)(c) * See regulation 8(1)(c)
1 pH 6.5 to 8.5 5.5 to 9 5.5 to 9
2 Coloration (after simple filtration) mg/1 Pt Scale 10 50 50
3 Total suspended solids mg/1 SS 25
4 Temperature °C 22 22 22
5 Conductivity at 20°C μs/cm 1000 1000 1000
6 Odour dilution factor at 25°C 3 10 20
7[^f01004] Nitrates mg/1 NO₃ 25
8[^f01002] Fluorides mg/1 F 0.7 to 1 0.7 to 1.7 0.7 to 1.7
10[^f01004] Dissolved iron mg/1 Fe 0.1 1 1
11[^f01004] Manganese mg/1 Mn 0.05 0.1 1
12 Copper mg/1 Cu 0.02 0.05 1
13 Zinc mg/1 Zn 0.5 1 1
14 Boron mg/1 B 1 1 1
19 Arsenic mg/1 As 0.01 0.05
20 Cadmium mg/1 Cd 0.001 0.001 0.001
24 Mercury mg/1 Hg 0.0005 0.0005 0.0005
27 Sulphates mg/1 SO₄ 150 150 150
28 Chlorides mg/1 Cl 200 200 200
29 Surfactants (reacting with methyl blue) mg/1 (laurylsulphate) 0.2 0.2 0.5
30[^f01004][^f01003] Phosphates mg/1 P₂O₅ 0.4 0.7 0.7
31 Phenols (phenol index) paranitroaniline 4-aminoantipyrine mg/1 C₆H₅OH 0.001 0.01
32 Dissolved or emulsified hydro carbons (after extraction by petroleum ether) mg/1 0.5
35[^f01004] Chemical oxygen demand (COD) mg/1 O₂ 30
36[^f01004] Dissolved oxygen saturation rate % O₂ >70 >50 >30
37[^f01004] Biochemical oxygen demand (BOD₅) (at 20°C without nitrification) mg/1 O₂ <3 <5 <7
38 Nitrogen Kjeldahl method (except NO₃) mg/1 N 1 2 3
39 Ammonia mg/1 NH₄ 0.05 1 2
40 Substances extractable with chloroform mg/1 SEC 0.1 0.2 0.5
43 Total coliforms 37°C /100ml 50 5,000 50,000
44 Faecal coliforms /100ml 20 2,000 20,000
45 Faecal streptococci /100ml 20 1,000 10,000
46 Salmonella Not present in 5,000ml Not present in 1,000ml

SCHEDULE 3

PART 1 — METHOD OF MEASURING THE VALUES OF PARAMETERS

No. in Annex I to the 1975 Directive Parameters Parameters Limit of detection[^f01016] Precision[^f01017] Accuracy[^f01018] Method of measurement Materials recommended for the container
General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic. General note: Samples taken at the abstraction point are analysed and measured after sieving (wire mesh sieve) to remove any floating debris such as wood or plastic.
1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit. 1 For waters classified as DW1, Schedule 2 limit.
2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3. 2 For waters classified as DW2 and DW3.
3 For waters classified as DW3. 3 For waters classified as DW3. 3 For waters classified as DW3. 3 For waters classified as DW3. 3 For waters classified as DW3. 3 For waters classified as DW3. 3 For waters classified as DW3. 3 For waters classified as DW3.
4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit. 4 For waters classified as DW1, DW2 and DW3, Schedule 1 limit.
5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3. 5 For waters classified as DW2, Schedule 1 limit, and DW3.
6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit. 6 For waters classified as DW2 and DW3, Schedule 2 limit.
7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene. 7 Mixture of six standard substances all of the same concentration to be taken into consideration: fluoranthene; 3, 4-benzofluoranthene; 11, 12-benzofluranthene; 3, 4-benzopyrene; 1, 12-benzoperylene; indano/1, 2, 3-ed/pyrene.
8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin. 8 Mixture of three substances all of the same concentration to be taken into consideration: parathion, hexachlorocyclohexane, dieldrin.
9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured. 9 If the samples contain so much suspended matter as to require special preliminary treatment, the accuracy values shown in this Part of Schedule 3 may as an exception be exceeded and will be regarded as a target. These samples must be treated so as to ensure that the analysis covers the largest quantity of substances to be measured.
10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained. 10 As this method is not in current use in all Member States it is not certain that the limit of detection required for checking values in the 1975 Directive can be attained.
11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit). 11 Absence in 5,000 m1 (for waters classified DW1, Schedule 2 limit) and absence in 1,000 m1 (for waters classified DW2, Schedule 2 limit).
12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect. 12 “Limit of detection” means the minimum value of the parameter examined which it is possible to detect.
13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located. 13 “Precision” means the range within which 95% of the results of measurements made on a single sample, using the same method, are located.
14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained. 14 “Accuracy” means the difference between the true value of the parameter examined and the average experimental value obtained.
1 pH pH unit – 0.1 0.2 – Electrometry. Measured in situ at the time of sampling without prior treatment of the sample.
2 Coloration (after simple filtration) mg/1 Pt Scale 5 10% 20% – Filtering through a glass fibre membrane. Photometric method using platinum-cobalt scale.
3 Total suspended solids mg/1 SS – 5% 10% – Filtering through a 0.45μm filter membrane, drying at 105°C and weighing
– Centrifuging (for at least 5 mins with mean acceleration of 2,800 to 3,200g) drying at 105°C and weighing.
4 Temperature °C – 0.5 1 – Thermometry. Measured in situ at the time of sampling without prior treatment of the sample.
5 Conductivity at 20°C μs/cm – 5% 10% – Electrometry.
No. in Annex I to the 1975 Directive Parameters Parameters Limit of Precision[^f01017]detection[^f01016] Accuracy[^f01018] Method of measurement recommended for the container Materials
--- --- --- --- --- --- --- ---
6 Odour dilution factor at 25 °C – – – – By successive dilutions. Glass.
7 Nitrates mg/1 NO₃ 2 10% 20% – Molecular absorption spectrophotometry.
8 Fluorides mg/1 F 0.05 10% 20% Molecular absorption spectrophotometry after distillation if necessary. Ion selective electrodes.
10 Dissolved iron mg/1 Fe 0.02 10% 20% Atomic absorption spectrophotometry after filtering through a filter membrane (0.45μm). Molecular absorption spectrophotometry after filtering through a 0.45μm filter membrane.
11 Manganese mg/1 Mn 0.01[^f01005] 0.02[^f01006] 10% 10% 20% 20% Atomic absorption spectrophotometry Atomic absorption spectrophotometry Molecular absorption spectrophotometry.
12 Copper[^f01013] mg/1 Cu 0.005 0.02[^f01007] 10% 10% 20% 20% Atomic absorption spectrophotometry Polarography Atomic absorption spectrophotometry Molecular absorption spectrophotometry Polarography.
No. in Annex I to the 1975 Directive Parameters Parameters Limit of detection[^f01016] Precision[^f01017] Accuracy[^f01018] Method of measurement Materials recommended for the container
13 Zinc[^f01013] mg/1 Zn 0.01[^f01005] 0.02 10% 10% 20% 20% Atomic absorption spectrophotometry Atomic absorption spectrophotometry Molecular absorption spectrophotometry.
14 Boron[^f01013] mg/1 B 0.1 10% 20% Molecular absorption spectrophotometry Atomic absorption spectrophotometry Materials not containing boron in any significant quantities.
19 Arsenic[^f01013] mg/1 As 0.002[^f01005] 0.01[^f01008] 20% 20% Atomic absorption spectrophotometry Atomic absorption spectrophotometry Molecular absorption spectrophotometry.
20 Cadmium[^f01013] mg/1 Cd 0.0002 0.0015 30% 30% Atomic absorption spectrophotometry Polarography.
21 Total Chromium[^f01013] mg/1 Cr 0.01 20% 30% Atomic Absorption spectrophotometry Molecular absorption spectrophotometry.
22 Lead[^f01013] mg/1 Pb 0.01 20% 30% Atomic absorption spectrophotometry Polarography.
23 Selenium[^f01013] mg/1 Se 0.005 – Atomic absorption spectrophotometry.
24 Mercury[^f01013] mg/1 Hg 0.0001 0.0002[^f01009] 30% 30% – Flameless atomic absorption spectrophotometry (cold vaporisation).
25 Barium[^f01013] mg/1 Ba 0.02 15% 30% – Atomic absorption spectrophotometry.
26 Cyanide mg/1 CN 0.01 20% 30% – Molecular absorption spectrophotometry.
27 Sulphates mg/1 SO₄ 10 10% 10% Gravimetric analysis. EDTA compleximetry. Molecular absorption spectrophotometry.
28 Chlorides mg/1 C1 10 10% 10% Titration (Mohr’s method). Molecular absorption spectrophotometry.
29 Surfactants (reacting with methylene blue) mg/1 (laury1 sulphate) 0.05 20% – Molecular absorption spectrophotometry.
30 Phosphates mg/1 P₂O₅ 0.02 10% 20% – Molecular absorption spectrophotometry.
31 Phenols (phenol Index) mg/1 C₆H₅OH 0.0005 0.0015 0.0005 30% 0.0005 50% Molecular absorption spectrophotometry 4-aminoantipyrine method. Paranitraniline method. Glass.
32 Dissolved or emulsified hydrocarbons mg/1 0.01 0.04[^f01006] 20% 30% Infra-red spectrometry after extraction by carbon tetrachloride Gravimetry after extraction by petroleum ether. Glass.
33 Polycyclic aromatic hydrocarbons[^f01013] mg/1 0.00004 50% 50% – Measurement of fluorescence in the UV after thin layer chromatography. Comparative measurement in relation to a mixture of six control substances with the same concentration[^f01011]. Glass or aluminium.
34 Total pesticides (parathion, hexachlorocyclohexane, dieldrin)[^f01013] mg/1 0.0001 50% 50% – Gas or liquid chromatography after extraction by suitable solvents and purification. Identification of the constituents of the mixture. Quantitative analysis[^f01012]. Glass.
35 Chemical oxygen demand (COD) mg/1 0₂ 15 20% 20% – Potassium dichromate method.
36 Dissolved oxygen saturation rate % 5 10% 10% Winkler’s method Electrochemical method. Glass.
37 Biochemical oxygen demand (BOD₅) at 20°C without nitrification mg/1 0₂ 2 1.5 2 – Determination of dissolved oxygen before and after five day incubation at 20 °C ± 1°C in complete darkness. Addition of a nitrification inhibitor.
38 Nitrogen by Kjeldahl method (except in NO₂ and NO₃) mg/1 N 0.3 0.5 0.5 – Mineralisation, distillation by Kjeldahl method and ammonium determination by means of molecular absorption spectrophotometry or titration.
39 Ammonium mg/1 NH₄ 0.01[^f01005] 0.1[^f01006] 0.03[^f01005] 10%[^f01006] 0.03[^f01005] 20%[^f01011] – Molecular absorption spectrophotometry.
40 Substances extractable with chloroform mg/l [^f01014] – Extraction at neutral pH value by purified chloroform, evaporation in vacuo at room temperature, weighing of residue.
43 Total coliforms /100ml 5[^f01005] 500[^f01010] Culture at 37 °C on an appropriate specific solid medium (such as Tergitol lactose agar, Endo agar, 0.4% Teepol broth) with filtration[^f01005] or without filtration[^f01010] and colony count. Samples must be diluted or, where appropriate, concentrated in such a way as to contain between 10 and 100 colonies. If necessary, identification by gasification. Method of dilution with fermentation in liquid substrates in at least three tubes in three dilutions. Sub-culturing of the positive tubes on a confirmation medium. Count according to MPN (most probable number). Incubation temperature: 37°C ± 1 °C. Sterilised glass.
44 Faecal coliforms /100ml 2[^f01005] 200[^f01010] Culture at 44 °C on an appropriate specific solid medium (such as Tergitol lactose agar, Endo agar, 0.4% Teepol broth) with filtration[^f01005] or without filtration[^f01010] and colony count. Samples must be diluted or, where appropriate, concentrated in such a way as to contain between 10 and 100 colonies. If necessary, identification by gasification. Method of dilution with fermentation in liquid substrates in at least three tubes in three dilutions. Sub-culturing of the positive tubes on a confirmation medium. Count according to MPN (most probable number). Incubation temperature 44 °C ± 0.5 °C. Sterilised glass.
45 Faecal streptococci /100 ml 2[^f01005] 200[^f01010] Culture at 37 °C on an appropriate solid medium (such as sodium azide) with filtration[^f01005] or without filtration[^f01010] and colony count. Samples must be diluted or, where appropriate concentrated in such a way as to contain between 10 and 100 colonies. Method of dilution in sodium azide broth in at least three tubes in three dilutions. Count according to MPN (most probable number). Sterilised glass.
46 Salmonella[^f01015] 1/5,000ml 1/1,000ml Concentration by filtration (on membrane or appropriate filter). Inoculation into pre-enrichment medium. Enrichment and transfer into isolating gelese – Identification. Sterilised glass.

SCHEDULE 3

PART II — MINIMUM ANNUAL FREQUENCY OF SAMPLING FOR EACH PARAMETER

Population served Classification DW1 Classification DW1 Classification DW1 Classification DW2 Classification DW2 Classification DW2 Classification DW3 Classification DW3 Classification DW3
I[^f01019] II[^f01020] III[^f01021] I[^f01019] II[^f01020] III[^f01021] I[^f01019] II[^f01020] III[^f01021]
1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium. 1 This column applies to the parameters – pH, coloration, total suspended solids, temperature, conductivity, odour, nitrates, chlorides, phosphates, chemical oxygen demand (COD), dissolved oxygen saturation rate, biochemical oxygen demand (BOD₅) and ammonium.
2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms. 2 This column applies to the parameters – dissolved iron, manganese, copper, zinc, sulphates, surfactants, phenols, nitrogen by the Kjeldahl method, total coliforms and faecal coliforms.
3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella. 3 This column applies to the parameters – fluorides, boron, arsenic, cadmium, total chromium, lead, selenium, mercury, barium, cyanide, dissolved or emulsified hydrocarbons, polycyclic aromatic hydrocarbons, total pesticides, substances extractable with chloroform, faecal streptococci and salmonella.
≤10,000 1 1 1 1 1 1 2 1 1
>10,000 to ≤30,000 1 1 1 2 1 1 3 1 1
>30,000 to ≤100,000 2 1 1 4 2 1 6 2 1
>100,000 3 2 1 8 4 1 12 4 1

Signed

George Kynoch — Parliamentary Under Secretary of State Scottish Office — 3rd December 1996

Explanatory note

(This note is not part of the Regulations)

These Regulations prescribe a system for classifying the quality of inland waters according to their suitability for abstraction for supply as drinking water, in implementation of Directive 75/440/EEC (quality required of surface water intended for the abstraction of drinking water). They provide mandatory values for classifications DW1, DW2 and DW3 in Schedule 1 to the Regulations and guideline values for those classifications in Schedule 2 to the Regulations.

The Regulations also incorporate the methods of measurement and frequency of sampling and analysis for those values, laid down in Directive 79/869/EEC (methods of measurement and frequencies of sampling and analysis of surface water intended for the abstraction of drinking water).

These Regulations, together with regulation 23 of the Water Supply (Water Quality) (Scotland) Regulations 1990, complete the implementation of Directives 75/440/EEC and 79/869/EEC for Scotland.

A compliance cost assessment of the effect that these Regulations would have on the cost of business is available from the Water Services Unit, Water Team, The Scottish Office, Victoria Quay, Edinburgh, EH6 6QQ.

Footnotes

[^f00001]: 1974 c. 40: section 30B was inserted, as part of a substitution of a new Part II of the Act, by the Water Act 1989 (c. 15) section 169 and Schedule 23, paragraph 4.

[^f00002]: S.I. 1989/2393.

[^f00003]: 1972 c. 68.

[^f00004]: OJ No L194, 25.7.75 p26.

[^f00005]: OJ No L229, 30.8.80 p11.

[^f00006]: OJ No L375, 31.12.91 p1.

[^f00007]: OJ No L271, 29.10.79, p44.

[^f00008]: 1994 c. 39.

[^f00009]: 1974 c. 40; section 41 was inserted by section 169 and paragraph 4 of Schedule 23 to the Water Act 1989 (c. 15) and was amended by section 120 and paragraph 29(10), (17), (18) and (19) of Schedule 22 to the Environment Act 1995 (c. 25).

[^f00010]: Section 30A(1)(c) was inserted by section 169 and paragraph 4 of Schedule 23 to the Water Act 1989 (c. 15).

[^f00011]: 1974 c. 40: section 30C was inserted by section 169 and paragraph 4 of Schedule 23 to the Water Act 1989 (c. 15) and was amended by section 120 and paragraph 29(2) and (4) of Schedule 22 to the Environment Act 1995 (c. 25).

[^f00012]: S.I. 1990/119; relevant amendments were made by S.I. 1991/1333.

[^f00013]: S.I. 1990/121.

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